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In some embodiments, the non-naturally occurring microbial organism additional includes a 1,4-butanediol pathway, the 1,4-butanediol pathway converting acetyl-CoA to 1,four-butanediol, wherein the 1,4-butanediol pathway consists of at least five enzymes chosen from 1) Acetoacetyl-CoA thiolase (AtoB), 2) 3-Hydroxybutyryl-CoA dehydrogenase (Hbd), three) Crotonase (Crt), 4) Crotonyl-CoA hydratase (four-Budh), 5) 4-hydroxybutyryl-CoA reductase (alcohol forming), 6) 4-hydroxybutyryl-CoA reductase (aldehyde forming), 7) 1,4-butanediol dehydrogenase, eight) four-Hydroxybutyryl-CoA transferase, 4-Hydroxybutyryl-CoA synthetase, 4-Hydroxybutyryl-CoA hydrolase, or Phosphotrans-four-hydroxybutyrylase/4-Hydroxybutyrate kinase, and 9) four-Hydroxybutyrate reductase. 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